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Preparation of Polypentafluorophenyl acrylate Functionalized SiO2 Beads for Protein Purification

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Multipurpose Polymeric Coating for Functionalizing Inert Polymer Surfaces.

A Evren Özçam, Kirill Efimenko, Richard J Spontak

¹Materials Measurement Science Division, National Institute of Standards and Technology , Gaithersburg, Maryland 20899, United States.

ACS Applied Materials & Interfaces

|January 28, 2016

Summary

This summary is machine-generated.

A new polymer coating, PVMS-TCS, is developed for versatile surface functionalization. This primer enables organosilane deposition and polymer brush growth on diverse substrates, including hydrophobic plastics.

Keywords:

NEXAFS PET PVMS semifluorinated silicones surface modification trichlorosilane ultraviolet/ozone treatment

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Area of Science:

Materials Science
Polymer Chemistry
Surface Science

Background:

Developing versatile polymer coatings is crucial for advanced material applications.
Functionalizing diverse polymeric substrates, especially hydrophobic ones, remains a challenge.

Purpose of the Study:

To report the development of a highly functionalizable polymer coating, PVMS-TCS.
To demonstrate its utility as a primer for surface modification on various substrates.

Main Methods:

Chemical coupling of trichlorosilane (TCS) to poly(vinylmethyl siloxane) (PVMS).
Coating PVMS-TCS onto diverse polymeric substrates (hydrophilic and hydrophobic).
Characterization using SEM, contact-angle, ellipsometry, FTIR, XPS, and NEXAFS.

Main Results:

PVMS-TCS serves as an effective primer layer on a wide range of polymers.
It facilitates organosilane deposition and polymer brush growth, even on hydrophobic surfaces like PET and polypropylene.
Comprehensive characterization confirmed the coating's physical and chemical properties.

Conclusions:

PVMS-TCS is a highly functionalizable and versatile polymer coating.
It offers a convenient method for modifying diverse surfaces, enabling advanced material functionalities.