Ionic Grease Lubricants: Protic [Triethanolamine][Oleic Acid] and Aprotic [Choline][Oleic Acid]
Liwen Mu1, Yijun Shi2, Tuo Ji1
1Intelligent Composites Laboratory, Department of Chemical and Biomolecular Engineering, The University of Akron , Akron, Ohio 44325 United States.
Abstract:
Ionic liquid lubricants or lubricant additives have been studied intensively over past decades. However, ionic grease serving as lubricant has rarely been investigated so far. In this work, novel protic [triethanolamine][oleic acid] and aprotic [choline][oleic acid] ionic greases are successfully synthesized. These ionic greases can be directly used as lubricants without adding thickeners or other additives. Their distinct thermal and rheological properties are investigated and are well-correlated to their tribological properties. It is revealed that aprotic ionic grease shows superior temperature- and pressure-tolerant lubrication properties over those of protic ionic grease. The lubrication mechanism is studied, and it reveals that strong physical adsorption of ionic grease onto friction surface plays a dominating role for promoted lubrication instead of tribo-chemical film formation.
Related Concept Videos
Synthesis of Phosphatidylcholine in the ER Membrane
The major components of all eukaryotic cell...
Design Example: Deciding Thickness of Lubricating Fluid in a Shaft
To calculate the required thickness of the lubricant layer, the tangential velocity at the shaft's surface must first be determined. This velocity is calculated by converting the rotational speed to angular velocity...
Indirect-Acting Cholinergic Agonists: Mechanism of Action
Reversible inhibitors like edrophonium bind to a specific part of the enzyme called the anionic catalytic site. They form noncovalent bonds, which means they are not strongly attached to the enzyme. This creates a temporary and less stable enzyme–inhibitor complex,...


