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Updated: Mar 26, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Capturing HBCy2: Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration
Marcus W Drover1, Laurel L Schafer2, Jennifer A Love3
1Department of Chemistry, The University of British Columbia, Vancouver, BC, V6T 1Z1, Canada.
Abstract:
1,3-N,O-chelated complexes of Rh(I) and Ir(I) cooperatively and reversibly stabilized the B-H bond of HBCy2 to afford six-membered metallaheterocycles (M=Rh (7) or Ir (8)) having a δ-[M]⋅⋅⋅H-B agostic interaction. Treatment of these Shimoi-type borane adducts 7 or 8 with both an aldehyde and an alkene resulted in chemoselective aldehyde hydroboration and reformation of the 1,3-N,O-chelated starting material. The observed chemoselectivity is inverted from that of free HBCy2 , which is selective for alkene hydroboration.
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