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Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
Published on: February 11, 2016
Photochemical water oxidation by cyclometalated iridium(iii) complexes: a mechanistic insight
Sujay Mukhopadhyay1, Roop Shikha Singh, Arnab Biswas
1Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi-221 005, UP, India. dspbhu@bhu.ac.in.
Abstract:
The proficiency of the cyclometalated iridium complexes [(η(5)-C5Me5)IrCl(L1)] (1), [(η(5)-C5Me5)IrCl(L2)] (2) and [(η(5)-C5Me5)IrCl(L3)] (3) has been examined towards photochemical water oxidation. The involvement of Ir(iv/v) in the catalytic process has been explored via CV, UV/vis, XPS spectroscopic studies and appreciable TON relative to the theoretical value of 1 from GC.
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