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Dye molecule bonded titanium alkoxide: a possible new type of dye for sensitized solar cells

Hu-Chao Su1, Yin-Yin Wu1, Jin-Le Hou1

  • 1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, People's Republic of China. zhuqinyu@suda.edu.cn daijie@suda.edu.cn.

Chemical Communications (Cambridge, England)
|February 23, 2016
PubMed

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.
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