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endo-Functionalized molecular tubes: selective encapsulation of neutral molecules in non-polar media
Guobao Huang1, Arto Valkonen2, Kari Rissanen2
1Department of Chemistry, South University of Science and Technology of China, No. 1088 Xueyuan Blvd, Nanshan District, Shenzhen 518055, P. R. China. jiangw@sustc.edu.cn and School of Chemistry and Environment, South China Normal University, Guangzhou, 510006, P. R. China.
Abstract:
Four endo-functionalized molecular tubes with urea/thiourea groups in the deep cavities have been synthesized, and their binding ability to neutral molecules studied. Very high binding affinity and selectivity have been achieved, which are rationalized by invoking the shape and electrostatic complementarity and dipole alignment.
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