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Updated: Mar 24, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Polymer-containing Organo-Polyoxometalate: Towards New Catalytic Object
1Laboratoire LHCEP (UMR 5278) Université Claude Bernard Lyon 1, Villeurbanne, France. emmanuel.lacote@univ-lyon1.fr.
Abstract:
Polyoxometalates (POMs) are early transition metal oxide clusters, which form a diverse family of compounds with highly tunable shapes, sizes, charges, etc. Generating hybrid structures is an attractive path to increase the structural diversity of POMs. The present article is a personal account that retraces how we inserted polyoxometallic platforms onto polymeric chains. We focused on two main families of functionalized organo-POMs: the organotin-substituted Dawson polyoxotunstates α1 and α2-[P(2)W(17)O(61)(SnR)](7-) and the Dawson vanadotungstates [P(2)V(3)W(15)O(59){(OCH(2))(2)-C(Et)NHC(=O)R}](5-). Herein we discuss how the connection of POMs to polymers affects the self-assembly of the polymers and the catalytic properties of the polyoxometalates.
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