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Multicomponent self-assembly of a pentanuclear Ir-Zn heterometal-organic polyhedron for carbon dioxide fixation and
Xuezhao Li1, Jinguo Wu, Cheng He
1State Key Laboratory of Fine Chemicals, Dalian University of Technology Dalian, 116012, China. hecheng@dlut.edu.cn.
Abstract:
By incorporating a fac-tris(4-(2-pyridinyl)phenylamine)iridium as the backbone of the tripodal ligand to constrain the coordination geometry of Zn(II) ions, a pentanuclear Ir-Zn heterometal-organic luminescent polyhedron was obtained via a subcomponent self-assembly for carbon dioxide fixation and sulfite sequestration.
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