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Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiOx Hole Contacts
Xingtian Yin1, Peng Chen1, Meidan Que1
1Electronic Materials Research Laboratory, International Center for Dielectric Research, Key Laboratory of the Ministry of Education, School of Electronic & Information Engineering, ‡Center of Nanomaterials for Renewable Energy (CNRE), State Key Lab of Electrical Insulation and Power Equipment, School of Electrical Engineering, and §State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University , Xi'an 710049, Shaanxi People's Republic of China.
Abstract:
A solution-derived NiOx film was employed as the hole contact of a flexible organic-inorganic hybrid perovskite solar cell. The NiOx film, which was spin coated from presynthesized NiOx nanoparticles solution, can extract holes and block electrons efficiently, without any other post-treatments. An optimal power conversion efficiency (PCE) of 16.47% was demonstrated in the NiOx-based perovskite solar cell on an ITO-glass substrate, which is much higher than that of the perovskite solar cells using high temperature-derived NiOx film contacts. The low-temperature deposition process made the NiOx films suitable for flexible devices. NiOx-based flexible perovskite solar cells were fabricated on ITO-PEN substrates, and a preliminary PCE of 13.43% was achieved.

