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![Solid-phase Synthesis of [4.4] Spirocyclic Oximes](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F58508.jpg&w=3840&q=50)
Solid-phase Synthesis of [4.4] Spirocyclic Oximes
Published on: February 6, 2019
O,S-Heterocyclic stannylenes: synthesis and reactivity
Surendar Karwasara1, Chandan Kumar Jha1, Soumen Sinhababu1
1Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India. sisn@chemistry.iitd.ac.in.
Abstract:
Commercially available N-oxide (2-mercaptopyridine-N-oxide) is used as a ligand instead of an oxidizing agent to stabilize the compounds of main group elements in low-valent states. The isolated compounds [(C5H4NOS)2Sn (), (C5H4NOS)SnCl () and (C5H4NOS)GeCl ()] are the first structurally characterized examples of O,S-heterocyclic stannylenes and germylenes with interesting bonding features. Further, the reaction of compound with SbCl3 afforded the rare dichlorodiantimony oxide [{(C5H4NOS)SbCl}2O] () unprecedentedly.
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