Plasmon-Induced Broadband Light-Harvesting for Dye-Sensitized Solar Cells Using a Mixture of Gold Nanocrystals

The efficiency of dye-sensitized solar cells (DSSCs) is generally limited by the mismatch between the absorption spectrum of the photosensitizer and the solar irradiation spectrum. This work describes the use of a mixture that containing proper proportions of SiO2 coated Au nanospheres (AuNSs@SiO2 ) and Au nanorods (AuNRs@SiO2 ) (the mixture was denoted as AuNCs@SiO2 ) to enhance the sunlight utility in DSSCs. The incorporation of AuNCs@SiO2 into the TiO2 photoanode induced broadband light-harvesting at both low- and long- wavelengths and thus enhanced the photocurrent compared to that of plasmonic solar cells based on either AuNSs@SiO2 or AuNRs@SiO2 . Upon the doping of AuNCs@SiO2 , the overall power conversion efficiency (PCE) increased from 7.39 to 9.12 % for DSSCs based on organic liquid electrolytes.