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Updated: Mar 21, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Photoacid-mediated ring opening polymerization driven by visible light
Changkui Fu1, Jiangtao Xu, Cyrille Boyer
1Centre for Advanced Macromolecular Design (CAMD) and Australian Centre for NanoMedicine (ACN), School of Chemical Engineering, UNSW Australia, Sydney, NSW 2052, Australia. cboyer@unsw.edu.au j.xu@unsw.edu.au.
Abstract:
A novel methodology of visible light regulated ring opening polymerization in the presence of reversible merocyanine-based photoacid was reported for the first time. In combination with a photoinduced radical polymerization technique, a dual wavelength light controlled orthogonal polymerization system was investigated to switch the polymerization between two different monomers and for the preparation of block and graft copolymers in one pot.
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