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Published on: May 20, 2014
Superdiffusion in dispersions of active colloids driven by an external field and their sedimentation equilibrium
Yen-Fu Chen1, Hsien-Hung Wei2, Yu-Jane Sheng1
1Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan 106, Republic of China.
Abstract:
The diffusive behaviors of active colloids with run-and-tumble movement are explored by dissipative particle dynamics simulations for self-propelled particles (force dipole) and external field-driven particles (point force). The self-diffusion of tracers (solvent) is investigated as well. The influences of the active force, run time, and concentration associated with active particles are studied. For the system of self-propelled particles, the normal diffusion is observed for both active particles and tracers. The diffusivity of the former is significantly greater than that of the latter. For the system of field-driven particles, the superdiffusion is seen for both active particles and tracers. In contrast, it is found that the anomalous diffusion exponent of the former is slightly less than that of the latter. The anomalous diffusion is caused by the many-body, long-range hydrodynamic interactions. In spite of the superdiffusion, the sedimentation equilibrium of field-driven particles can be acquired and the density profile is still exponentially decayed. The sedimentation length of field-driven particles is always greater than that of self-propelled particles.
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