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Synthesis, Structure, and Photochemical Behavior of [5]Heli-viologen Isomers
Xiaoping Zhang1, Edward L Clennan1, Navamoney Arulsamy1
1Department of Chemistry, University of Wyoming , Laramie, Wyoming 82071, United States.
Abstract:
The syntheses of isomeric helical viologens that have potential applications in supramolecular chemistry and catalysis have been developed. The structures of the molecules and their solid-state packing motifs have been determined by X-ray crystallography. Computational studies demonstrate that the magnitude of their racemization barriers is primarily determined by the identity of the helical scaffold and is insensitive to the placement of the viologen functional group. The isomers are similar in their photophysical behavior but very different in their photochemical behavior.
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