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Related Concept Videos

Hydrogen Bonds00:26

Hydrogen Bonds

136.1K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
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Hydrogen Bonds01:04

Hydrogen Bonds

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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
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Recodable surfaces based on switchable hydrogen bonds.

Nils Wedler-Jasinski1, Nicolas Delbosc2, Marie-Alice Virolleaud2

  • 1Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany. christopher.barner-kowollik@kit.edu and Soft Matter Synthesis Laboratory, Institut für Biologische Grenzflächen (IBG), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany.

Chemical Communications (Cambridge, England)
|June 25, 2016
PubMed
Summary

Researchers developed novel recodable surfaces using reversible hydrogen bonds. These surfaces allow repeated attachment and removal of polymers via photochemical control, enabling dynamic surface patterning.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Surface Chemistry

Background:

  • Developing dynamic and rewritable surfaces is crucial for advanced materials.
  • Existing surface modification techniques often lack reversibility or spatial control.

Purpose of the Study:

  • To introduce and demonstrate recodable surfaces based on reversible artificial hydrogen bonding.
  • To achieve spatially resolved, repeated immobilization and cleavage of polymers on surfaces.

Main Methods:

  • Utilizing symmetrical oligoamide (SOA) attached to poly(methyl methacrylate) (PMMA).
  • Employing photochemically functionalized asymmetric oligoamides (AOAs) on surface domains.
  • Analyzing recodability using Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS).

Main Results:

  • Demonstrated successful repeated immobilization and cleavage of SOA-PMMA.
  • Achieved spatially defined surface recodability through photochemical control.
  • Quantified the recoding process using ToF-SIMS imaging.

Conclusions:

  • Recodable surfaces based on reversible hydrogen bonding are feasible.
  • Photochemical control enables dynamic and reversible surface functionalization.
  • This approach offers a new platform for creating switchable material interfaces.