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Dramatic Changes in the Solubilities of Ions Induced by Ligand Addition in Biphasic System D2O/DNO3//[C1C4im][Tf2N]:
Dariia Ternova1, Maria Boltoeva2,3, Laure Cointeaux4,5
1Institute of Organic Chemistry, NASU , Murmanska Street 5, 02660 Kyiv-94, Ukraine.
Abstract:
The solubilities of C1C4im(+) and Tf2N(-) in nitric aqueous phases have been measured for several ligand types and concentrations (0.04 M tributylphosphine oxide, 0.05 M N,N'-dimethyl-N,N'-dibutylmalonamide, 0.10 M 1-methyl-3-[4-(dibutylphosphinoyl)butyl]-3H-imidazol-1-ium bis(trifluoromethylsulphonyl)imidate, and 1.1 M N,N-dihexyloctanamide). The data evidence a significant difference between the solubilities of the cations and anions of the ionic liquid as a consequence of several ion-exchange and/or ion-pairing mechanisms involving all ions present in the system as well as the protonation/nitric-extraction ability of the ligand.
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