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Stereochemical Difference in Secoisolariciresinol Formation between Cell-free Extracts from Petioles and from
Bioscience, Biotechnology, and Biochemistry
|July 12, 2016
Abstract:
Cell-free extracts from ripening seeds of Arctium lappa L. catalyzed the enantioselective formation of (-)-pinoresinol, (-)-lariciresinol and (-)-secoisolariciresinol from achiral coniferyl alcohol in the presence of NADPH and H2O2. The enantioselectivity of the lignan formation was opposite to that of the (+)-secoisolariciresinol formation catalyzed by cell-free extracts from petioles of the same plant species.
