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Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands
Rajendhraprasad Tatikonda1, Sandip Bhowmik1, Kari Rissanen1
1University of Jyväskylä, Department of Chemistry, P.O. Box 35, FI-40014 University of Jyväskylä, Finland.
Abstract:
Terpyridine based ligands 1 and 2, decorated with a C8F17 perfluorinated tag, are able to form stable thermoreversible gels in the presence of several d-block metal chloride salts. The gel systems obtained have been characterized by NMR, X-ray diffraction, electron microscopies and Tgel experiments in order to gain insights into the observed different behaviour of the two similar ligands, also in terms of the effect of additional common anionic species.
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