Complete Oxidation of Toluene Over Supported Palladium Catalysts: Effect of Support
Abstract:
The catalytic oxidation of toluene was carried out to investigate the effect of the support on the properties and performance of a supported palladium catalyst (1 wt% loading). γ-Al2O3), SiO2 and TiO2 were used as supports. The properties of the prepared catalysts were characterized by XRD, BET, PT, TPD, TPR, XPS and FE-TEM analyses. The experimental results showed that the order of catalytic performance was 1 wt% Pd/TiO2 > 1 wt% Pd/SiO2 > 1 wt% Pd/γ-Al2O3. A strong interaction between the palladium and support was found, which affected the palladium surface concentration and particle size. The higher catalytic activity of the Pd/TiO2 catalyst was attributed to the higher palladium surface concentration and larger particle size.
More Related Videos
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
10:19Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
Related Concept Videos
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Reactions at the Benzylic Position: Oxidation and Reduction
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids
