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Updated: Mar 14, 2026
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Template-based Synthesis of a Formate Metal-Organic Framework/Activated Carbon Fiber Composite for High-performance
Xiao-Wei Liu1,2, Jiang-Liang Hu1,2, Tian-Jun Sun1
1Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, P. R. China.
Abstract:
Simultaneous improvement in adsorption selectivity and capacity for single adsorbents is challenging but counting for much in adsorptive separations. To this end, a formate metal-organic framework and activated carbon fiber composite was synthesized in our work by a simple two-step process, involving homogeneous precipitation of a MOF precursor on an activated carbon fiber and subsequent template replication. The resultant core-shell composite, ACF@[Ni3 (HCOO)6 ], exhibited optimized adsorption performance both in selectivity and capacity for the separation of CH4 /N2 to most of state-of-the-art adsorbents.
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