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Updated: Mar 14, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Oligomerization of N-Heterocyclic Silylene into Zwitterionic Silenes
Alexander V Zabula1,2, Ilia A Guzei3, Robert West3
1P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 S. 34th St., Philadelphia, PA, 19104, USA. avzabula@gmail.com.
Abstract:
N-Heterocyclic carbenes (NHC's) are known to serve as efficient substrates for the stabilization of various transient species possessing low-valent Group 14 elements and for the generation of double E=C bonds. Herein, we report that the thermal tri- and tetramerizations of pyridoannulated silylene 1 lead to the formation of remarkably stable silenes 2 and 3 featuring zwitterionic distribution of electron density. Co-oligomerization of 1 and its germanium analogue gives a related tetrameric product 4 containing low-valent germanium atom stabilized by binding with the partial carbene-character C atom. Bonding situations in 2-4 are best described as silene or germene with the significant zwitterionic distribution of electron density. The singlet diradical electronic state of 2 is 10 kcal mol-1 higher than the ground state configuration.
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