Related Experiment Video
Updated: Mar 14, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Correction: Selective precipitation of alkyl dihalides using a newly synthesized water-soluble
Wenjin Cheng1, Hao Tang2, Rongrong Wang1
1School of Chemistry and Chemical Engineering, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510641, China. drcao@scut.edu.cn.
Abstract:
Correction for 'Selective precipitation of alkyl dihalides using a newly synthesized water-soluble bisphosphorylpillar[5]arene' by Wenjin Cheng et al., Chem. Commun., 2016, 52, 8075-8078.
Related Concept Videos
Formation of Halohydrin from Alkenes
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...
Acid Halides to Alcohols: LiAlH4 Reduction
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
Preparation of Alkynes: Dehydrohalogenation
Alkynes can be prepared by dehydrohalogenation of vicinal or geminal dihalides in the presence of a strong base like sodium amide in liquid ammonia. The reaction proceeds with the loss of two equivalents of hydrogen halide (HX) via two successive E2 elimination reactions.
Preparation and Reactions of Sulfides

