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Updated: Mar 13, 2026
Synthesis and Functionalization of 3D Nano-graphene Materials: Graphene Aerogels and Graphene Macro Assemblies
Published on: November 5, 2015
Synchronous exfoliation and assembly of graphene on 3D Ni(OH)2 for supercapacitors
Liguo Ma1, Maojun Zheng2, Shaohua Liu3
1Key Laboratory of Artificial Structure and Quantum Control, Ministry of Education, Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China. mjzheng@sjtu.edu.cn.
Abstract:
Nowadays, new approaches to fabricate high-performance electrode materials are of vital importance in the renewable energy field. Here, we present a facile synthesis procedure of 3D Ni(OH)2/graphene hybrids for supercapacitors via synchronous electrochemical-assisted exfoliation and assembly of graphene on 3D Ni(OH)2 networks. With the assistance of an electric field, the electrochemically exfoliated high-quality graphene can be readily, uniformly assembled on the surfaces of 3D Ni(OH)2. When serving as electrode materials for supercapacitors, the resulting 3D Ni(OH)2/graphene composites exhibited excellent specific capacitance (263 mF cm-2 at 2 mA cm-2), remarkable rate capability and super-long cycle life (retention of 94.1% even after 10 000 continuous charge-discharge cycles), which may be attributed to their highly porous, stable 3D architecture as well as uniform, firm anchoring of ultrathin graphene on their surfaces. Therefore, our approach provides a facile strategy for the large-scale synthesis of high-quality graphene based composites towards various applications.
