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A Selective Colorimetric and Turn-on Fluorescent Chemosensor for Hg2+ in Aqueous Solution
Yi-Ru Chiou1, Chin-Feng Wan2, An-Tai Wu3
1Department of Chemistry, National Changhua University of Education, Changhua, 50058, Taiwan.
Abstract:
A simple colorimetric and turn-on fluorescence receptor FT (thiophene appended fluorescein-hydrazone derivative) was prepared and its cation-sensing properties were investigated. Receptor FT displayed a selective colorimetric change (from colorless to orange color) upon binding to Hg2+ in DMSO/H2O (1:9, v/v) solution. The association constant of FT-Hg2+ complex was calculated to be 3.03 × 109 M-1, and the detection limit for Hg2+ was found to be 0.24 ppm.
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