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Updated: Mar 12, 2026

A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration
Published on: March 29, 2019
Facile Way of Synthesis for Molybdenum Iodides
Markus Ströbele1, Robert Thalwitzer1, H-Jürgen Meyer1
1Section for Solid State and Theoretical Inorganic Chemistry, Institute of Inorganic Chemistry, University of Tübingen , Auf der Morgenstelle 18, 72076 Tübingen, Germany.
Abstract:
Molybdenum iodides are prepared based on a new way of synthesis, namely, via reductive metathesis reaction of MoCl5 with SiI4. MoI3 was formed at 150 °C. Mo6I12 and the new molybdenum iodides Mo6I16 and Mo6I18 with the well-known [Mo6I8]4+ cluster core were obtained in the temperature range 550-600 °C. Compounds were structurally characterized by powder and single-crystal X-ray diffraction techniques.
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