Related Experiment Video

Updated: Mar 12, 2026

Electrospray Deposition of Uniform Thickness Ge23Sb7S70 and As40S60 Chalcogenide Glass Films
08:38

Electrospray Deposition of Uniform Thickness Ge23Sb7S70 and As40S60 Chalcogenide Glass Films

Published on: August 19, 2016

9.1K

Mid-infrared nonlinear absorption in As2S3 chalcogenide glass

Francis Théberge, Pierre Mathieu, Nicolas Thiré

    Optics Express
    |November 10, 2016
    PubMed
    Summary

    Mid-infrared nonlinear absorption in arsenic trisulfide (As2S3) glasses is significantly stronger than previously thought. This intrinsic property, driven by two-photon excitation, impacts high-power fiber applications.

    More Related Videos

    In-situ Tapering of Chalcogenide Fiber for Mid-infrared Supercontinuum Generation09:39

    In-situ Tapering of Chalcogenide Fiber for Mid-infrared Supercontinuum Generation

    Published on: May 27, 2013

    12.8K
    Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion06:48

    Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion

    Published on: May 9, 2025

    1.3K

    Related Concept Videos

    Molecular Spectroscopy: Absorption and Emission01:14

    Molecular Spectroscopy: Absorption and Emission

    Molecules possess discrete energy levels called quantum states. Unlike atoms, which have simpler energy levels, molecules possess additional rotational and vibrational energy levels.  Each energy level is separated by an energy gap, with the gaps between adjacent electronic, vibrational, and rotational levels varying significantly. The three types of energy levels in a diatomic molecule are shown in Figure 1.
    5.2K
    IR Spectroscopy: Molecular Vibration Overview01:24

    IR Spectroscopy: Molecular Vibration Overview

    When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental vibrational motions that result in infrared absorption can be classified as stretching or bending vibrations.
    Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
    5.6K
    UV–Vis Spectroscopy of Conjugated Systems01:32

    UV–Vis Spectroscopy of Conjugated Systems

    Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
    One of the factors influencing λmax is the extent of conjugation in...
    8.8K
    IR Absorption Frequency: Delocalization01:04

    IR Absorption Frequency: Delocalization

    Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or bond. This phenomenon is common in systems with conjugated bonds—structures where alternating single and double bonds allow π-electrons to move freely across the network. The movement of electrons stabilizes the molecule and can affect various chemical properties, including vibrational frequencies observed in IR spectroscopy.
    In IR...
    1.6K
    IR Absorption Frequency: Hybridization01:21

    IR Absorption Frequency: Hybridization

    Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
    Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that...
    1.5K
    UV–Vis Spectroscopy: Molecular Electronic Transitions01:16

    UV–Vis Spectroscopy: Molecular Electronic Transitions

    In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this...
    3.3K