Related Experiment Video
Updated: Mar 12, 2026

Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light
Published on: September 12, 2014
Dark states enhance the photocell power via phononic dissipation
Yiteng Zhang1, Aaron Wirthwein2, Fahhad H Alharbi3
1Department of Physics, Purdue University, West Lafayette, IN 47907, USA.
Abstract:
The high efficiency of the photon-to-charge conversion process found in photosynthetic complexes has inspired researchers to explore a new route for designing artificial photovoltaic materials. Quantum coherence can provide a mean to surpass the Shockley-Quiesser device concept limit by reducing the radiative recombination. Taking inspiration from these new discoveries, we consider a linearly-aligned system as a light-harvesting antennae composed of two-level optical emitters coupled with each other by dipole-dipole interactions. Our simulations show that the certain dark states can enhance the power with the aid of intra-band phononic dissipation. Due to cooperative effects, the output power will be improved when incorporating more emitters in the linear system.
Related Concept Videos
Photoelectric Effect
Deactivation Processes: Jablonski Diagram
P-N junction
Photoluminescence: Fluorescence and Phosphorescence
A pair of electrons in a...
Variables Affecting Phosphorescence and Fluorescence
Interference and Diffraction

