The classification and representation of main group element compounds that feature three-center four-electron...

This article provides a means to classify and represent compounds that feature 3-center 4-electron (3c-4e) interactions in terms of the number of electrons that each atom contributes to the interaction. Specifically, Class I 3c-4e interactions are classified as those in which two atoms provide one electron each and the third atom provides a pair of electrons (i.e. LX₂), while Class II 3c-4e interactions are classified as those in which two atoms each provide a pair of electrons and the third atom contributes none (i.e. L₂Z). These classes can be subcategorized according to the nature of the central atom. Thus, Class I interactions can be categorized according to whether the central atom provides one (i.e.μ-X) or two (i.e.μ-L) electrons, while Class II interactions can be categorized according to whether the central atom provides none (i.e.μ-Z) or two (i.e.μ-L) electrons. The use of appropriate structure-bonding representations for these various interactions provides a means to determine the covalent bond classification of the element of interest.