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Related Concept Videos

Stereoisomers02:32

Stereoisomers

19.0K
On the basis of mirror symmetry, stereoisomers of an organic molecule can be further classified into diastereomers and enantiomers. Diastereomers are stereoisomers that are not mirror images of each other. Substituted alkenes, such as the cis and trans isomers of 2-butene, are diastereomers, as these molecules exhibit different spatial orientations of their constituent atoms, are not mirror images of each other, and do not interconvert. Here, the interconversion is suppressed due to...
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Stereoisomerism02:52

Stereoisomerism

14.3K
Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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Stereoisomerism of Cyclic Compounds02:33

Stereoisomerism of Cyclic Compounds

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In this lesson, we delve into the role of ring conformation and its stability, which determines the spatial arrangement and, consequently, the molecular symmetry and stereoisomerism of cyclic compounds. 1,2-Dimethylcyclohexane is used as a case study to evaluate the possible number of stereoisomers. Here, given the multiple (n = 2) chiral centers, there are 2n = 4 possible configurations that lack a plane of symmetry, as the ring skeleton exists in a non-planar chair conformation. In addition,...
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Stereochemical Effects of Enolization01:12

Stereochemical Effects of Enolization

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The chiral α-carbon of the carbonyl compound is the stereocenter of the molecule. As shown in the figure below, when such a carbonyl compound undergoes racemization under an acidic or basic condition, an achiral enol is formed.
2.7K
Polymer Classification: Stereospecificity01:26

Polymer Classification: Stereospecificity

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Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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Fischer Projections02:18

Fischer Projections

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Learning to draw Fischer projections of molecules and understanding their relevance plays a crucial role in the visual depiction of organic molecules. A Fischer projection is a two-dimensional projection on a planar surface to simplify the three-dimensional wedge–dash representation of molecules. This is especially helpful in the case of molecules with multiple chiral centers that can be difficult to draw. Here, all the bonds of interest are represented as horizontal or vertical lines. While...
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Measuring Sensitivity to Viewpoint Change with and without Stereoscopic Cues
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Stereo Object Proposals.

Shao Huang, Weiqiang Wang, Shengfeng He

    IEEE Transactions on Image Processing : a Publication of the IEEE Signal Processing Society
    |November 17, 2016
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    Summary
    This summary is machine-generated.

    This study introduces a novel object proposal detection method using stereopsis, improving accuracy in cluttered scenes. The approach enhances object recognition by leveraging depth and color cues for robust proposal generation.

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    Area of Science:

    • Computer Vision
    • Machine Learning
    • Robotics

    Background:

    • Object proposal detection accelerates object recognition but struggles with cluttered backgrounds using boundary-based methods.
    • Existing methods often fail to effectively identify objects in complex visual environments.

    Purpose of the Study:

    • To develop a robust object proposal detection method leveraging stereopsis for improved accuracy.
    • To address limitations of traditional boundary-based methods in cluttered scenes.

    Main Methods:

    • Utilized stereopsis with adaptive transformation for candidate bounding box generation based on depth and color information.
    • Developed a two-level hierarchy (proposal and cluster levels) for efficient and accurate object location estimation.
    • Introduced three stereo-based cues (exactness, focus, distribution) for objectness estimation and two-level hierarchical ranking for proposal refinement.

    Main Results:

    • A new stereo dataset with 400 labeled stereo image pairs was created for indoor and outdoor scene evaluation.
    • The proposed stereo-based approach demonstrated superior performance compared to state-of-the-art methods across varying numbers of object proposals.
    • Stereopsis proved to be a valuable complement to color information for object proposal generation.

    Conclusions:

    • Stereopsis offers a robust solution for object proposal detection, particularly effective in challenging, cluttered environments.
    • The proposed method enhances object recognition accuracy and can be integrated with existing techniques for superior results.