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Modular Polymer Biosensors by Solvent Immersion Imprint Lithography.

J S Moore1, S S Xantheas2, J W Grate2

  • 1Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.

Journal of Polymer Science. Part B, Polymer Physics
|November 22, 2016
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Summary
This summary is machine-generated.

Solvent Immersion Lithography (SIIL) enables rapid prototyping of polymer sensors. This technique enhances molecular O2 detection by achieving higher doping concentrations and improving sensor performance.

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Area of Science:

  • Materials Science
  • Sensor Technology
  • Chemical Engineering

Background:

  • Solvent Immersion Lithography (SIIL) is a rapid prototyping technique for microsystems.
  • Previous work demonstrated SIIL for polymer functionalization, imprinting, and bonding.

Purpose of the Study:

  • To realize planar polymer sensors using SIIL via simple solvent immersion without imprinting.
  • To characterize the impregnation properties and doping enhancement of SIIL.
  • To develop and assess optical sensors for molecular O2 detection using SIIL.

Main Methods:

  • Utilized SIIL with simple solvent immersion for polymer sensor fabrication.
  • Investigated SIIL's impregnation characteristics and doping concentrations.
  • Developed and characterized optical sensors for molecular O2 detection.
  • Controlled sensor performance via immersion duration.

Main Results:

  • Achieved practical doping concentrations with an unexpected 2-fold enhancement compared to immersion solutions.
  • Developed optical sensors for molecular O2 detection with a high dynamic range.
  • Demonstrated control over sensor dynamic range through immersion duration, showcasing SIIL's modularity.

Conclusions:

  • SIIL accelerates polymer sensor prototyping by requiring minimal processing time and no specialized equipment.
  • SIIL enhances the operating characteristics of polymer sensors, particularly for O2 detection.
  • The technique is broadly applicable to sensors for any polymer-permeable reactant.