Organic Planar Heterojunctions: From Models for Interfaces in Bulk Heterojunctions to High-Performance Solar Cells

Recent progress regarding planar heterojunctions (PHJs) is reviewed, with respect to the fundamental understanding of the photophysical processes at the donor/acceptor interfaces in organic photovoltaic devices (OPVs). The current state of OPV research is summarized and the advantages of PHJs as models for exploring the relationship between organic interfaces and device characteristics described. The preparation methods and the characterization of PHJ structures to provide key points for the appropriate handling of PHJs. Next, we describe the effects of the donor/acceptor interface on each photoelectric conversion process are reviewed by examining various PHJ systems to clarify what is currently known and not known. Finally, it is discussed how we the knowledge obtained by studies of PHJs can be used to overcome the current limits of OPV efficiency.