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Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
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Design principles for nonequilibrium self-assembly.

Michael Nguyen1,2, Suriyanarayanan Vaikuntanathan3,2

  • 1Department of Chemistry, The University of Chicago, Chicago, IL, 60637.

Proceedings of the National Academy of Sciences of the United States of America
|December 3, 2016
PubMed
Summary
This summary is machine-generated.

We derived design principles for controlled self-assembly far from equilibrium using stochastic thermodynamics. These principles guide the creation of specific configurations under non-equilibrium conditions, modifying equilibrium landscapes.

Keywords:
nonequilibrium self-assemblypattern formationsecond law of thermodynamicsself-assemblystochastic thermodynamics

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Area of Science:

  • Thermodynamics
  • Statistical Mechanics
  • Materials Science

Background:

  • Self-assembly is crucial for creating complex structures.
  • Equilibrium self-assembly is well-understood but limited.
  • Far-from-equilibrium systems offer new possibilities for controlled assembly.

Purpose of the Study:

  • To derive design principles for controlled self-assembly far from equilibrium.
  • To understand how non-equilibrium conditions modify self-assembly landscapes.
  • To provide a theoretical framework for designing novel self-assembled materials.

Main Methods:

  • Utilizing the formalism of stochastic thermodynamics.
  • Analyzing the constraints imposed by non-equilibrium conditions on assembly pathways.
  • Developing theoretical models for finite non-equilibrium drive.

Main Results:

  • A set of design principles for controlled self-assembly under non-equilibrium conditions.
  • Identification of constraints on achievable configurations.
  • Insights into the modification of equilibrium self-assembly landscapes.

Conclusions:

  • Stochastic thermodynamics provides a powerful framework for designing self-assembly processes.
  • Controlled self-assembly far from equilibrium is achievable with specific design principles.
  • Understanding non-equilibrium effects is key to expanding the capabilities of self-assembly.