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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

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Transposed Paternò-Büchi Reaction.

Elango Kumarasamy1, Ramya Raghunathan1, Sunil Kumar Kandappa1

  • 1Department of Chemistry and Biochemistry, North Dakota State University , Fargo, North Dakota 58108, United States.

Journal of the American Chemical Society
|December 14, 2016
PubMed
Summary

Researchers explored a new photochemical strategy using alkene excited states in a transposed Paternò-Büchi reaction. This approach enables control over stereochemistry in reactions involving atropisomeric enamides.

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