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Work, work fluctuations, and the work distribution in a thermal nonequilibrium steady state
T R Kirkpatrick1, J R Dorfman1, J V Sengers1
1Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, USA.
This study introduces Casimir work for nonequilibrium fluids, revealing its connection to heat, not energy. Anomalous work fluctuations and distributions are highlighted, differing significantly from equilibrium systems.
Area of Science:
- Non-equilibrium statistical mechanics
- Fluid dynamics
- Condensed matter physics
Background:
- Long-ranged correlations are inherent in non-equilibrium fluid systems, particularly strong in steady states driven by temperature gradients.
- Anomalous light scattering and Casimir forces in these systems have been subjects of recent detailed discussion.
- Existing formal theories lack explicitness in detailing work and work distribution features in non-equilibrium steady states.
Purpose of the Study:
- Introduce the concept of Casimir work in non-equilibrium systems.
- Propose an alternative method for measuring non-equilibrium Casimir forces.
- Investigate and contrast work fluctuations and distributions in non-equilibrium versus equilibrium systems.
Main Methods:
- Definition and introduction of Casimir work for non-equilibrium systems.
- Relating non-equilibrium Casimir force to non-equilibrium heat.
- Computation and analysis of non-equilibrium work fluctuations and work distributions.
Main Results:
- The non-equilibrium Casimir force is shown to be related to non-equilibrium heat, distinct from equilibrium systems where it relates to energy derivatives.
- Non-equilibrium work fluctuations exhibit anomalous behavior compared to equilibrium work fluctuations.
- Computed non-equilibrium work distributions display striking differences when contrasted with those in systems exhibiting short-range correlations.
Conclusions:
- The study provides a novel perspective on Casimir forces in non-equilibrium systems by introducing Casimir work.
- A new experimental approach for measuring non-equilibrium Casimir forces is suggested, linked to heat rather than energy.
- The anomalous nature of work fluctuations and distributions in non-equilibrium steady states is quantitatively demonstrated, highlighting limitations of current formal theories.
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