Chestnut-Like TiO₂@α-Fe₂O₃ Core-Shell Nanostructures with Abundant Interfaces for Efficient and Ultralong Life...

Transition metal oxides caused much attention owing to the scientific interests and potential applications in energy storage systems. In this study, a free-standing three-dimensional (3D) chestnut-like TiO₂@α-Fe₂O₃ core-shell nanostructure (TFN) is rationally synthesized and utilized as a carbon-free electrode for lithium-ion batteries (LIBs). Two new interfaces between anatase TiO₂ and α-Fe₂O₃ are observed and supposed to provide synergistic effect. The TiO₂ microsphere framework significantly improves the mechanical stability, while the α-Fe₂O₃ provides large capacity. The abundant boundary structures offer the possibility for interfacial lithium storage and electron transport. The as-prepared TFN delivers a high capacity of 820 mAh g^-1 even after 1000 continuous cycles with a Coulombic efficiency of ca. 99% at a current of 500 mA g^-1, which is better than the works reported previously. A thin gel-like SEI (solid electrolyte interphase) film and Fe⁰ phase yielded during charge/discharge cycling have been confirmed which makes it possible to alleviate the volumetric change and enhance the electronic conductivity. This confirmation is helpful for understanding the mechanism of lithium-ion storage in α-Fe₂O₃-based materials. The as-prepared free-standing TFN with excellent stability and high capacity can be an appropriate candidate for carbon-free anode material in LIBs.