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Updated: Mar 10, 2026

Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
Published on: January 7, 2022
A new concept of charging supercapacitors based on the photovoltaic effect
Saran Kalasina1, Pichaya Pattanasattayavong2, Montakan Suksomboon1
1Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand. montree.s@vistec.ac.th.
Abstract:
A significant enhancement in the areal capacitance of a Co(OH)2 supercapacitor charged and discharged under light illumination is clearly observed, with the capacitance about two-fold higher than that operated under dark conditions. This is because Co(OH)2 has an energy band gap of 2.85 eV and can absorb blue light and generate photoelectrons via the photovoltaic effect, leading to high current density.
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