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Updated: Mar 10, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly
Hasti Iranmanesh, Kasun S A Arachchige, Mohan Bhadbhade
1School of Chemistry and Molecular Biosciences, The University of Queensland , Brisbane, Queensland, Australia.
Abstract:
A series of enantiopure ruthenium(II) polypyridyl complexes are reported that feature pendant pyridyl groups suitable for building larger self-assembled structures. The complexes are characterized in detail in solution using NMR spectroscopy, cyclic voltammetry, and photophysical methods and in the solid state using single-crystal X-ray crystallography. The complexes are luminescent, displaying long excited-state lifetimes that are quenched when the pendant pyridyl groups are protonated. Reaction with cadmium(II) ions results in the formation of a mixed-metal one-dimensional coordination polymer, which was characterized by single-crystal X-ray crystallography.
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