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Excited-State Intramolecular Proton Transfer and Global Aromaticity

Naoko Nishina1, Toshiki Mutai2, Jun-Ichi Aihara1

  • 1Department of Chemistry, Faculty of Science, Shizuoka University , Oya, Shizuoka 422-8529, Japan.

The Journal of Physical Chemistry. A
|December 22, 2016
PubMed
Summary

Global aromaticity influences excited-state intramolecular proton transfer (ESIPT) reactions. Enhanced aromaticity in the tautomeric product generally facilitates ESIPT, while decreased aromaticity can create an energy barrier, impacting reaction feasibility.

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