Degree of Conversion and Polymerization Shrinkage of Bulk-Fill Resin-Based Composites

This study evaluated the degree of conversion (DC) and polymerization shrinkage (PS) of contemporary bulk-fill resin-based composites (RBCs) including giomer materials. Two giomer bulk-fill (Beautifil Bulk Restorative [BBR], Beautifil Bulk Flowable [BBF]), two nongiomer bulk-fill (Tetric N-Ceram Bulk-fill [TNB], Smart Dentin Replacement [SDR]), and three conventional non-bulk-fill (Beautifil II [BT], Beautifil Flow Plus [BF], Tetric N-Ceram [TN]) RBCs were selected for the study. To evaluate the DC, disc-shaped specimens of 5-mm diameter and 2-mm, 4-mm, and 6-mm thickness were fabricated using customized Teflon molds. The molds were bulk filled with the various RBCs and cured for 20 seconds using a light-emitting diode curing light with an irradiance of 950 mW/cm². The DC (n=3) was determined by attenuated total reflectance Fourier transform infrared spectroscopy by computing the spectra of cured and uncured specimens. PS (n=3) was measured with the Acuvol volumetric shrinkage analyzer by calculating specimen volumes before and after light curing. The mean DC for the various materials ranged from 46.03% to 69.86%, 45.94% to 69.38%, and 30.65% to 67.85% for 2 mm, 4 mm, and 6 mm, respectively. For all depths, SDR had the highest DC. While no significant difference in DC was observed between depths of 2 mm and 4 mm for the bulk-fill RBCs, DC at 2 mm was significantly greater than 6 mm. For the conventional RBCs, DC at 2 mm was significantly higher than at 4 mm and 6 mm. Mean PS ranged from 1.48% to 4.26% for BBR and BF, respectively. The DC at 2 mm and PS of bulk-fill RBCs were lower than their conventional counterparts. At 4 mm, the DC of giomer bulk-fill RBCs was lower than that of nongiomer bulk-fill materials.