Related Experiment Video
Updated: Mar 9, 2026

10:27
The Evolution of Silica Nanoparticle-polyester Coatings on Surfaces Exposed to Sunlight
Published on: October 11, 2016
10.0K
Image Evaluation of the High Resolution VUV Spectrometer at SURF II by Ray Tracing
N C Das1, R P Madden2, H M Seyoum3
1Spectroscopy Division, Bhabha Atomic Research Center, Bombay2400 085, India.
Summary
Researchers optimized a VUV spectroscopic facility at NIST for better spectral resolution. Tilting the entrance slit significantly reduced spectral line widths, achieving high resolution for VUV spectroscopy.
Area of Science:
- Spectroscopy
- Optical Physics
- Synchrotron Radiation
Background:
- A high-resolution Vacuum Ultraviolet (VUV) spectroscopic facility has been operational at the Synchrotron Ultraviolet Radiation Facility (SURF II) at the National Institute of Standards and Technology (NIST).
- The facility utilizes a sophisticated optical setup including three cylindrical mirrors and a concave grating spectrometer in an off-plane Eagle mounting.
Purpose of the Study:
- To prepare for the installation of an array detector by developing a ray tracing program.
- To analyze and optimize the spectral image quality, specifically line widths, of the VUV spectroscopic facility.
- To evaluate the achievable spectral widths for VUV spectroscopy using an array detector.
Main Methods:
- Development of a ray tracing program to simulate optical performance.
- Construction of spot diagrams by plotting ray intersections with the image plane.
- Investigation of parallel and tilted entrance slit configurations relative to the grating grooves.
- Estimation of spectral widths for recorded images on an array detector.
Main Results:
- Ray tracing simulations and spot diagram analysis were performed.
- It was demonstrated that tilting the entrance slit can reduce spectral image line widths.
- Estimated spectral widths of 0.41 pm to 0.88 pm in first order were achieved for the 40 nm to 120 nm wavelength region.
Conclusions:
- The VUV spectroscopic facility at SURF II can achieve high spectral resolution.
- Optimizing the entrance slit configuration is crucial for minimizing spectral line widths.
- The facility is well-suited for VUV spectroscopy applications requiring precise spectral measurements in the 40-120 nm range.
Related Concept Videos
UV–Vis Spectrometers
4.2K
The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
4.2K
Ultraviolet and Visible (UV–Vis) Spectroscopy: Overview
8.3K
Ultraviolet–visible (UV–visible or UV–Vis) spectroscopy is an analytical technique that investigates the interaction between matter and UV–Vis light within the electromagnetic spectrum. This method is widely used for its versatility, simplicity, and relatively quick data acquisition, making it valuable for both qualitative and quantitative analysis. When UV–Vis radiation passes through a material, molecules absorb light depending on the energy required for...
8.3K
UV–Vis Spectrum
3.1K
When light passes through a substance, a portion of the light is absorbed while the remaining light is reflected or transmitted. If the molecule absorbs light between the wavelengths of 180–400 nm range, the UV spectrum is obtained, and if it absorbs light in the 400–780 nm wavelength range, the visible spectrum is obtained.
The UV–Vis spectrum of a molecule is the plot of its absorbance versus wavelength. The plot is drawn by taking molar...
The UV–Vis spectrum of a molecule is the plot of its absorbance versus wavelength. The plot is drawn by taking molar...
3.1K
UV–Vis Spectroscopy: Woodward–Fieser Rules
29.1K
UV–Visible absorption spectra of conjugated dienes arise from the lowest energy π → π* transitions. The light-absorbing part of the molecule is called the chromophore, and the substituents directly attached to the chromophore are called auxochromes. A strong correlation exists between the absorption maxima, λmax, and the structure of a conjugated π system. The Woodward–Fieser rules predict the value of λmax for a given structure by adding the...
29.1K

