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Updated: Mar 9, 2026
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal-Organic Framework
Yun-Long Wu1, Jinjie Qian2, Guo-Ping Yang1
1Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University , Xi'an 710127, China.
Abstract:
An unusual porous metal-organic framework has been synthesized by using Pb(II) and rigid V-shaped 4,4'-(pyridine-3,5-diyl)diisophthalic acid (H4L). Structure analysis reveals that there exist 1D cylindrical 14.26 Å and triangular prism 10.69 × 10.69 × 10.69 Å3 nanotubes in the framework. Gas sorption behavior of the nanoporous MOF shows a relatively high capacity and selectivity of CO2 over CH4.
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