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Updated: Mar 9, 2026

Ultrafast Time-resolved Near-IR Stimulated Raman Measurements of Functional π-conjugate Systems
Published on: February 10, 2020
Study of the transient "free" OH radical generated in H2O-H2O2 mixtures by stimulated Raman scattering
Fangfang Li1, Zhiwei Ma1, Shenghan Wang1
1Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College of Physics, Jilin University, Changchun 130012, China.
Abstract:
Forward and backward stimulated Raman scattering (SRS) were studied in the H2O2-H2O mixtures by a strong excitation laser with 532nm. Only the backward SRS (BSRS) of the H2O2-H2O system shows an unexpected SRS shoulder peak at around 3600cm-1, which is similar to the characteristic peak of "free" OH radical. The generation of the "free" OH radical is mainly attributed to the dissociation of hydrogen peroxide (HP) molecules. Simultaneously, the ionization of HP-water clusters generates a part of "free" OH radical under the Laser-induced breakdown (LIB). The interaction of water and HP is also discussed.
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