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Updated: Mar 9, 2026
11:27
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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Evolution of form in metal-organic frameworks.
Jiyoung Lee1, Ja Hun Kwak2, Wonyoung Choe1
1Department of Chemistry, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea.
Nature Communications
|January 5, 2017
Summary
Researchers developed a sequential self-assembly strategy for metal-organic materials (MOMs), enabling control over crystal interiors and creating diverse hollow and core-shell structures. This advance facilitates new applications in drug delivery and catalysis.
Area of Science:
- Materials Science
- Nanotechnology
- Supramolecular Chemistry
Background:
- Self-assembly is a key strategy for synthesizing functional metal-organic materials (MOMs), including metal-organic frameworks (MOFs) and metal-organic polyhedra (MOPs).
- Current self-assembly methods have limitations in controlling the internal structure of MOM crystals.
- Precisely controlling MOM internal structures is crucial for advanced material functionalities.
Purpose of the Study:
- To develop a sequential self-assembly strategy for synthesizing diverse MOM crystal forms.
- To demonstrate control over the interior of MOM crystals.
- To explore the potential of these MOMs in advanced applications like drug delivery and catalysis.
Main Methods:
- Utilized a sequential self-assembly approach.
- Employed single-crystal to single-crystal transformation from MOP to MOF.
- Synthesized various MOM crystal morphologies, including hollow and core-shell structures.
Main Results:
- Successfully synthesized diverse MOM crystal forms, including double-shell hollow MOMs.
- Demonstrated a form evolution in MOMs, yielding solid, core-shell, matryoshka, and hollow structures.
- Established a novel method for controlling the interior architecture of MOM crystals.
Conclusions:
- The sequential self-assembly strategy offers a new pathway for creating diverse MOM forms.
- This approach allows for precise control over MOM crystal interiors.
- The developed MOMs show promise for future applications in sequential drug delivery and heterogeneous cascade catalysis.
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