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Solution processing of two-dimensional black phosphorus.

Edward A Lewis1, Jack R Brent1, Brian Derby1

  • 1School of Materials, University of Manchester, M13 9PL, UK. david.lewis-4@manchester.ac.uk.

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|January 6, 2017
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Summary
This summary is machine-generated.

Two-dimensional black phosphorus (2D BP) offers tunable electronic properties for advanced applications. This review explores scalable solution-processing methods for 2D BP, addressing challenges like oxidation and highlighting future opportunities.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Phosphorene, or 2D black phosphorus (BP), is the first synthetic 2D elemental allotrope beyond graphene.
  • It exhibits high p-type carrier mobility and a tunable direct band gap (0.3-2 eV), bridging graphene and transition metal dichalcogenides.
  • Initial isolation used the 'Scotch-Tape' method, but scalable solution-processing techniques have since been developed.

Purpose of the Study:

  • To focus on solution-process routes for producing electronics-grade 2D black phosphorus (BP).
  • To highlight the challenges associated with processing 2D BP, particularly its susceptibility to oxidation.
  • To illuminate new avenues and opportunities in the field of 2D BP research and application.

Main Methods:

  • Review of solution-processing techniques for 2D black phosphorus (BP) synthesis and fabrication.
  • Analysis of material properties and processing challenges, focusing on oxidation sensitivity.
  • Exploration of emerging strategies and future research directions.

Main Results:

  • Scalable solution-processing techniques can yield electronics-grade 2D black phosphorus (BP).
  • Oxidation remains a significant challenge impacting the stability and processability of 2D BP.
  • New processing strategies are emerging to overcome these limitations.

Conclusions:

  • Solution-processing offers a scalable pathway for 2D black phosphorus (BP) integration into electronic devices.
  • Addressing oxidation susceptibility is crucial for unlocking the full potential of 2D BP.
  • Continued research into novel processing methods will drive advancements in 2D materials.