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Updated: Mar 9, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
An ultrastable zirconium-phosphonate framework as bifunctional catalyst for highly active CO2 chemical transformation
Chao-Ying Gao1, Jing Ai2, Hong-Rui Tian3
1College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao 02800, P. R. China and State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China. szm@ciac.ac.cn.
Abstract:
A zirconium-phosphonate network, as a bifunctional catalyst for carbon dioxide (CO2)/epoxide coupling reaction, exhibits very high activity that is superior to most documented metal-organic framework (MOF)-based catalysts. Furthermore, it possesses extraordinary tolerance to extremely harsh conditions, such as aqua regia. This paper describes the use of metal phosphonate as a new MOF applied to CO2 transformation.
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