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Effect of long-range electrostatic repulsion on pore clogging during microfiltration.

Sheng Chen1, Wenwei Liu1, Shuiqing Li1

  • 1Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China.

Physical Review. E
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Charged microparticle clogging is prevented by particle repulsion, which impacts pore-level flow and particle capture. A phase diagram shows the transition from clogging to non-clogging states based on pressure and charge.

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Area of Science:

  • Physics
  • Materials Science
  • Chemical Engineering

Background:

  • Clogging of pores by microparticles is a critical issue in filtration and fluid transport.
  • Understanding the interplay of interparticle forces is essential for controlling clogging dynamics.

Purpose of the Study:

  • To investigate the role of electrostatic repulsion in the clogging process of charged microparticles at the single-pore level.
  • To quantify the impact of Coulomb repulsion on bulk permeability, particle penetration, and capture efficiency.
  • To establish a clogging phase diagram and identify criteria for the clogging-nonclogging transition.

Main Methods:

  • Computer simulations utilizing adhesive contact mechanics.
  • Analysis of bulk permeability, number of penetrating particles, and particle capture efficiency.
  • Construction of a clogging phase diagram based on driving pressure and a charge parameter (κq).

Main Results:

  • Electrostatic repulsion between charged microparticles significantly delays or prevents clog formation.
  • A critical state, marked by minimum particle capture efficiency, serves as a non-clogging criterion for repulsive particles.
  • Clog structure is primarily governed by short-range adhesion, influencing particle penetration.

Conclusions:

  • Interparticle repulsion is a key factor in mitigating microparticle clogging.
  • The proposed clogging phase diagram and critical state provide valuable metrics for predicting and controlling clogging phenomena.
  • Both long-range repulsion and short-range adhesion dictate the overall clogging behavior and outcomes.