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Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR
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Effect of electron spectral diffusion on static dynamic nuclear polarization at 7 Tesla

Alisa Leavesley1, Daphna Shimon2, Ting Ann Siaw1

  • 1Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106, USA. songi@chem.ucsb.edu.

Physical Chemistry Chemical Physics : PCCP
|January 18, 2017
PubMed
Summary

This study explores dynamic nuclear polarization (DNP) in frozen water using electron paramagnetic resonance (EPR). Results show electron spectral diffusion significantly impacts DNP efficiency under specific conditions.

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