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Updated: Mar 8, 2026

Stereolithographic 3D Printing with Renewable Acrylates
Published on: September 12, 2018
Synthesis and characterization of a novel resin monomer with low viscosity
Lihua Hong1, Yu Wang2, Lin Wang3
1Endodontics Department of Stomatological Hospital, Jilin University, Changchun 130021, PR China; Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, PR China.
Objective:
In this study, we designed and synthesized a novel macromolecule (tetramethyl bisphenol F acrylate, TMBPF-Ac) with low viscosity, excellent mechanical properties, and good biocompatibility. It could be used as a monomer for dental resin composites, which could reduce the risk of human exposure to bisphenol A derivatives in the oral environment. In addition, the monomer could be used without diluent, thereby avoiding the negative effect of a diluent METHODS: TMBPF-Ac was synthesized by a multistep condensation reaction. Its structure was confirmed by 1H NMR spectra. Different resin mixtures were prepared, and then a number of performance and cytotoxicity tests were performed on these specimens.
Results:
1H NMR spectra showed that the structure of TMBPF-Ac was in accordance with the design. The viscosity of TMBPF-Ac was obviously lower than that of bisphenol-A diglycidyl methacrylate. The three kinds of resins used in this study were in line with ISO 4049:2009 and ISO 10993-5:2009. TMBPF-Ac-based resin had better physical and biological properties.
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