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Published on: April 16, 2017
In situ formation of reduced graphene oxide structures in ceria by combined sol-gel and solvothermal processing
Jingxia Yang1, Johannes Ofner2, Bernhard Lendl2
1Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9, 1060 Wien, Austria; permanent address: College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, LongTeng Road 333, 201620 Shanghai, P. R. China.
Abstract:
Raman and IR investigations indicated the presence of reduced graphene oxide (rGO)-like residues on ceria nanoparticles after solvothermal treatment in ethanol. The appearance of such structures is closely related to cerium tert-butoxide as precursor and ethanol as solvothermal solvent. The rGO-like residues improve the catalytic CO oxidation activity. This was also confirmed by introduction of "external" graphene oxide during sol-gel processing, by which the rGO structures and the catalytic activity were enhanced.

