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Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
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In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
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Updated: Mar 7, 2026

Deposition of Porous Sorbents on Fabric Supports
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Smoldering and Flame Resistant Textiles via Conformal Barrier Formation.

Mauro Zammarano1, Valeria Cazzetta2, Shonali Nazaré1

  • 1Flammability Reduction Group, Engineering Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, MD 20899-866, USA.

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Summary

A novel silicone backcoating prevents fabric fires by forming a protective layer. This fire retardant technology offers enhanced smoldering and flaming ignition resistance for textiles and flexible materials.

Keywords:
backcoatingfireflame-retardantsmolderingtextile

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Textile Engineering

Background:

  • Flammable textiles pose significant fire risks.
  • Existing fire retardant treatments often have limitations.

Purpose of the Study:

  • To develop a novel fire retardant mechanism for fabrics.
  • To impart smoldering and flaming ignition resistance to textiles.

Main Methods:

  • Application of a halogen-free, silicone-based backcoating to flammable fabric.
  • Investigating the thermal decomposition products and their subsequent oxidation.
  • Evaluating the formation of a protective coating on fabric fibers.

Main Results:

  • Cyclic siloxanes formed upon thermal decomposition and diffused through the fabric.
  • Oxidation of siloxanes created a conformal, thermally stable coating.
  • The coating effectively shielded fibers, preventing fabric combustion.

Conclusions:

  • A new fire retardant mechanism based on silicone backcoating was demonstrated.
  • This approach provides effective smoldering/flaming ignition resistance and fire-barrier properties.
  • The technology is applicable to textiles and multifunctional flexible materials.